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LPG marketed
in India confirms to Indian Standard
Specification IS-4576. Some of the important properties and their bearings are : LIQUID DENSITY
LP gases in the liqud state are nearly half
as heavy as water. Specific gravities range from 0.55 - 0.58. Knowledge of this property
helps us in calculating the safe quantities that can be filled in a given container whose
volume is known. An LPG container should be filled in such a way that there will be a 5%
ullage left at the design temperature, otherwise, as temperature rises excessive pressures
are likely to be encountered leading to bursting of cylinders.
CO-EFFICIENT OF EXPANSION OF LIQUID
Approximately 12 times that of water. This
property in conjunction with liquid density should be taken into consideration for
arriving at safe filling capacities of containers.
VAPOUR SPECIFIC GRAVITY LPG vapour is nearly 1 1/2 times to 2 times as heavy
as air. This would mean that any escaping vapour of LPG would tend to settle down. Hence,
there should be adequate ground level ventilation where LPG cylinders are stored.
For this very reason LPG cylinder
installations should not be undertaken in cellars or basements which have no ventilation
at ground level. Also, cylinders installation should not be within 1 meter of drain
opening.
VAPOUR PRESSURE The vapour of LPG in equilibrium with its liquid
exerts a pressure called the vapour pressure and the magnitude of this pressure is
dependent on the ambient temperature and not on the quantity of the contents. Vapour
pressure increases rapidly with temperature. Boiling point of a liquid is that temperature
at which the vapour pressure of the liquid equals atmospheric pressure. Since boiling point
of LPG is below 0 deg. C the pressure inside a cylinder is always higher than the
atmospheric pressure for temperatures above 0 deg C and hence, this is the reason that gas
gushes out of a cylinder when the valve is opened.
Hence, an external equipment i.e. pressure
regulator is needed for obtaining gas at a constant pressure for use in appliances
irrespective of the ambient temperature.
EXPLOSIVE LIMITSCombustible gases will only ignite with air when
mixed with it in certain proportion. As a combustible gas is gradually mixed with air in
increasing proportions, a concentration is reached at which the mixture just becomes
explosive i.e. ignitable. This is called the " Lower Explosive Limit"
As concentration of the gas is further
increased, a point is reached at which the mixture ceases to be ignitable, and the
concentration of the gas just before this point is called the "Upper Explosive
Limit"
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