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FURNACE OIL (FO)
DEFINITION :
A dark viscous residual fuel obtained by blending
mainly heavier components from crude distillation unit, short residue and clarified
oil from fluidized catalytic cracker unit.
NOMENCLATURE
Bunker fuel, furnace oil , Fuel oil are other
names for the same product. Though Fuel oil is a general term applied to any oil
used for generation of power or heat, Fuel oil can included distillates and blends
of distillates and residue such as Light Diesel Oil.
SPECIFICATION
Furnace oil in the current marketing range
meets Bureau of Indian Standards Specification IS : 1593 - 1982 for fuel oils, grade
MV2.
VISCOSITY
Viscosity is the most important characteristic
in the furnace oil specification. It influences the degree of pre-heat required
for handling, storage and satisfactory atomization. If the oil is too viscous it
may become difficult to pump, burner may be hard to light and operation may be erratic.
Poor atomization may result in the carbon deposits on the burner tips or on the
walls. The upper viscosity limit for furnace oil is such that it can be handled
without heating in the storage tank is excepting under server cold conditions. Pre-heating
is necessary for proper atomization.
FLASH POINT
As per the Controller of Explosives classification,
Furnace oil falls in the class "C" category with minimum flash point standard of
66 deg. C. Since Penskey Martens Closed Cup method is used, it is apparent that
a small quantity of low boiling point hydrocarbons is sufficient to lower the flash
point drastically.
POUR POINT
It is a very rough indication of the lowest
temperature at which Furnace Oil is readily pumpable. In the specification the pour
point of Furnace oil is not stipulated. However, for Furnace oil manufactured indigenously
and for imported parcels, the pour point is such that current supplies normally
can be handled without heating the fuel oil handling installation.
WATER
Water may be present in free or emulsified
form and can on combustion cause damage to the inside furnace surfaces especially
if it contains dissolved salts. It can also cause sputtering of the flame at the
burner tip. Water content of furnace oil when supplied is normally very low as the
product at refinery site is handled hot and maximum limit of 1% is specified in
the standard.
SEDIMENT
Furnace oil being a blend of residues contains
some quantity of sediments. These have adverse effect on the burners and cause blockage
of filters etc. However, the typical values are normally much lower than the stipulated
value of maximum 0.25 percent, by mass.
ASH
Ash is incombustible component of the furnace
oil and is expressed as a percentage mass of the furnace oil sample. Ash consists
of extraneous solids, residues of organometallic compounds in solution and salts
dissolved in water present in the fuel. These salts may be compounds of sodium,
vanadium, calcium magnesium, silicon, iron etc.
Ash has erosive effect on the burner tips,
causes damage to the refractories at high temperatures and gives rise to high temperature
corrosion and fouling of equipments.
SULPHUR
Sulphur determination includes burning of
known quantiy of oil, treating the sulphur oxidation products formed during combustion
and weighing of sulphur in the form of sulphate.
The sulphur di oxide may come in direct contact
with the product during the combustion process and may create adverse quality effects
in the product.
CALORIFIC VALUE
Calorific value of a fuel is the quantity
of heat generated in kilocalories by complete burning of one kilogram weight of
fuel. Gross calorific value is higher than net calorific value to the extent of
heat required to change water formed by combustion into water vapours.
